The last mention of Fr. Raphael in Patriarchal records is in the minutes of the Holy Synod of [[November 4]], 1908, which cite a letter from Fr. Raphael recommending an Anglican priest of Philadelphia, named "A.C.V. Cartier",<ref group="note">A.C.V. Cartier was ordained to the Episcopal deaconate by Bishop [[w:Charles Quintard|Charles Quintard]] in 1895, and ordained to the Episcopal priesthood in the same year by Bishop Quintard. (Bragg, Rev. George F. (D.D.). ''Chapter XXXVI: Negro Ordinations from 1866 to the Present''. In: '''[http://www.archive.org/details/historyofafroame00brag History of the Afro-American group of the Episcopal church (1922)].''' Baltimore, Md.: Church Advocate Press, 1922. p.273.)</ref> as a candidate for conversion to Orthodoxy and ordination as a priest. Cartier was rector of the [http://www.aecst.org/home.htm African Episcopal Church of St. Thomas], in Philadelphia, from 1906-12.<ref group="note">[[George Alexander McGuire]] was rector of The African Episcopal Church of St. Thomas in Philadelphia from 1902-05. He was succeeded as rector by A.C.V. Cartier (1906-12), the man whom Morgan recommended to the [[Church of Constantinople|Ecumenical Patriarchate]] for Orthodox ordination.</ref> Saint Thomas' served the African American elite of Philadelphia and was one of the most prestigious congregations in African American Christianity, having been started in 1794 by [[w:Absalom Jones|Absalom Jones]], one of the founders, together with [[w:Richard Allen (bishop)|Richard Allen]], of the [[w:w:African Methodist Episcopal Church|African Methodist Episcopal Church]].<ref name=Martin>Tony Martin. ''[http://books.google.ca/books?id=NgIYlUbaoAoC&printsec=frontcover&source=gbs_navlinks_s#v=onepage&q=&f=false McGuire, George Alexander].'' '''Encyclopedia of the Harlem Renaissance'''. Volume 2. Cary D. Wintz, Paul Finkelman (Eds.). Taylor & Francis, 2004. p.776.</ref> According to the letter, Cartier desired as an Orthodox priest to undertake missionary work among his fellow blacks. Due to the fact that the jurisdiction over the Greek Church of the [[diaspora]] had been ceded by the Ecumenical Patriarchate to the [[Church of Greece]] in 1908, the request was forwarded there. However according to Greek-American historian Paul G. Manolis, a search of the Archives of the Holy Synod of the Church of Greece did not turn up any correspondence with Fr. Raphael. His letter about A.C.V. Cartier is the only indication we have from Church records of his missionary efforts among his people.<ref name="MANOLIS"/>
In 1909, his wife filed for divorce, on the alleged charges of cruelty and failure to support their children. She left with their son Cyril to Delaware County, where she remarried.