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*Count [[Dmitry Andreyevich Tolstoy]] ([[June 23]], 1865 – [[April 23]], 1880).
*[[Constantine Petrovich Pobedonostsev|Constantine Pobedonostsev]] [[April 24]], 1880 – [[October 19]], 1905).
*Duke [[Alexis Dmitrievich Obolensky'|Alexander Dmitriyevich Obolensky]] ([[October 20]], 1905 – [[April 4]], 1906). See[[Talk:Alexis Dmitrievich Obolensky|discussion comment]]
*Duke Alexei Alexandrovich Shirinsky-Shikhmatov [[April 26]], 1906 – [[June 9]], 1906).
*Peter Petrovich Izvolsky ([[June 27]], 1906 – [[February 5]], 1909).